Benzene

Benzene is an organic chemical compound with the molecular formula C₆H₆.

Quotes

• I would trade all my experimental works for the single idea of the benzene theory.
  • August Wilhelm von Hofmann, Quoted by B. L. Lepsius in 'Hofmann und die Deutsche Chemische Gesellschaft', Berichte der Deutschen Chemischen Gesellschaft (1918), 51, 51.

• In the benzene nucleus we have been given a soil out of which we can see with surprise the already-known realm of organic chemistry multiply, not once or twice but three, four, live or six times just like an equivalent number of trees. What an amount of work had suddenly become necessary, and how quickly were busy hands found to carry it out! First the eye moves up the six stems opening out from the tremendous benzene trunk. But already the branches of the neighbouring stems have become intertwined, and a canopy of leaves has developed which becomes more spacious as the giant soars upwards into the air. The top of the tree rises into the' clouds where the eye cannot yet follow it. And to what an extent is this wonderful benzene tree thronged with blossoms! Everywhere in the sea of leaves one can spy the slender hydroxyl bud: hardly rarer is the forked blossom [Gabelblüte] which we call the amine group, the most frequent is the beautiful cross-shaped blossom we call the methyl group. And inside this embellishment of blossoms, what a richness of fruit, some of them shining in a wonderful blaze of color, others giving off an overwhelming fragrance.
  • August Wilhelm von Hofmann, after-dinner speech at Kekulé Benzolfest (Mar 1890). Trans. in W. H. Brock, O. Theodor Benfrey and Susanne Stark, 'Hofmann's Benzene Tree at the Kekulé Festivities', Journal of Chemical Education (1991), 68, 887-8.

• People have wracked their brains for an explanation of benzene and how the celebrated man [Kekulé] managed to come up with the concept of the benzene theory. With regard to the last point especially, a friend of mine who is a farmer and has a lively interest in chemistry has asked me a question which I would like to share with you. My 'agricultural friend' apparently believes he has traced the origins of the benzene theory. 'Has Kekulé,' so ran the question, 'once been a bee-keeper? You certainly know that bees too build hexagons; they know well that they can store the greatest amount of honey that way with the least amount of wax. I always liked it,' my agricultural friend went on, 'When I received a new issue of the Berichte; admittedly, I don't read the articles, but I like the pictures very much. The patterns of benzene, naphthalene and especially anthracene are indeed wonderful. When I look at the pictures I always have to think of the honeycombs of my bee hives.'
  • August Wilhelm von Hofmann, after-dinner speech at Kekulé Benzolfest (Mar 1890). Trans. in W. H. Brock, O. Theodor Benfrey and Susanne Stark, 'Hofmann's Benzene Tree at the Kekulé Festivities', Journal of Chemical Education (1991), 68, 888.

• We have demonstrated by exploiting an Armediated approach that (H₂O)⁶⁻ undergoes type I →II interconversion in the process of complex formation with benzene.
  • Ryuzo Nakanishi, Takeshi Sato, Kiyoshi Yagi, and Takashi Nagata, "Hydrogen-Bond Network Transformation in Water-Cluster Anions Induced by the Complex Formation with Benzene", J. Phys. Chem. Lett. 2012, 3, 3571−3575